The canonical pendulum demo is this:
http://www.youtube.com/watch?v=vQhNEw2seNs
It’s so well-known it was included in the recent BBC Challenger dramatisation of Feynman’s last great adventure, previously mentioned on this blog, only to my mind the dramatisation did it badly. With a longer pendulum drop the energy loss is minimal, and you really want your back and particularly the back of your head to be braced against a wall, as shown in the film above. If you stand in open space you’re at significant risk of swaying a little, and with a long enough pendulum you may have only millimetres of leeway.
It’s also one of those demos for which I’ve been wary of using volunteers. If they muck around at all they risk a bowling ball to the face, but sometimes a volunteer’s trust that you the performer wouldn’t let any harm come to them is stronger than their understanding of the physics. This is one of those situations where the science is considerably more reliable than the test subject.
Besides, I reckon the best way of performing this demo wouldn’t involve a person at all, but rather a priceless vase borrowed from a museum. Sadly, I’ve never seen it done that way.